The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+Cl / CCl3O2 / Catoire(1996)_298K_205-280nm(Gaussian fit)

DATAFILE: CCl3O2_Catoire(1996)_298K_205-280nm(Gaussian fit).txt
NAME: trichloromethylperoxy radical
FORMULA: CCl3O2
AUTHOR(YEAR): Catoire(1996)
T: 298K
λ: 205-280nm(Gaussian fit)
BIBLIOGRAPHY: V. Catoire, R. Lesclaux, W.F. Schneider, and T.J. Wallington, "Kinetics and mechanism of the self-reactions of CCl3O2 and CHCl2O2 radicals and their reactions with HO2", J. Phys. Chem. 100, 14356-14371 (1996); DOI: 10.1021/jp960572z
COMMENTS: Flash photolysis of Cl2/CHCl3/O2 mixtures coupled with absorption spectrometry

Calibration of the spectrum against the CH3O2 spectrum

Gaussian fit to the measured data points and the corrected data points of
Russell et al., J. Phys. Chem. 94 (1990) 3277; DOI: 10.1021/j100371a012

Fig. 1 digitized

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